博文

Combination Collector Mechanism--Adsorption Effect

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In flotation system of two or more than two collector mixture, through collection makes collector produces generate synergies, this kind of tungsten ore flotation collector called combination collector in the industry.  Practice has proved that many function of combination has better and more effective flotation effect than single collector, there are many opinions as for the effect. Combinations collector mechanism has the adsorption effect is comparing the identity and the mechanism of the most studied, some scholars think that mineral surface formed in the process of mineralization, the processing is uneven physical and chemical reagents of adsorption of mineralogy basis. Adsorption effect including physical adsorption, double electrode layer, synonym ion exchange adsorption, molecular adsorption and chemical adsorption. Total absorption effect is a variety of collector to produce interaction between each other, eventually lead to promote and strengthen the flot...

Classification of Tungsten Ore Flotation Reagents

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From dressing industrial progress of history suggests that mineral processing reagents application significance is self-evident. Since its discovery in 1924 xanthate has the function of collecting sulfide ore, the development of the flotation industry started by leaps and bounds, the inundated mineral processing reagents has been invented and created with a steady stream. However, how many dressing agent are they? How to classification, which is often confused about. In western countries, most of dressing agent were issued in the form of “patent certificate”. Therefore some names are quite chaotic, sometimes it only some numbers. At the same time, the dressing agent is more cheaper in general, other impure industrial by-product, its composition is not very sure; And several kinds of medicine emulsion mixture or the product of interactions, often name after the new potion. According to a German experts statistics, there are 7702 species the name of the material can be us...

Scheelite Flotation Collector—Y-17 Fatty Acid Sodium Salt

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In recent years, the fatty acid with microbial fermentation system of sulphide ore collector, has attracted a lot of interest, because it is a fatty acid collector substitute another very promising source, and confirmed by experiment. The effect is better than the average oleic acid substitute. Y-17 fatty acid sodium salt is the system of a microbe scheelite flotation collector developed by our country. Y-17 fatty acid sodium salt is in1974, Shanghai institute of organic chemistry research units such as microbial collector of success, is a kind of mixed fatty acid sodium salt. Its appearance is soft solid tan, containing unsaturated acid about 79%, hydroscopicity,soluble in water, its aqueous solution, 5% still not set at 5°C, used as a collector can use cold water can also be used as configured to any concentration of less than 10% of the hot water.  Hunan some tungsten mines to use Y-17 grade of WO 3  3.91% fatty acid sodium salt heating flotation of ...

The Scheelite Flotation Process—Lime Method

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In our country the white tungsten deposit is mostly a skarn shape deposit, this kind of characteristic of scheelite ore bed is “lean, multiple, thin, miscellaneous”, especially the “miscellaneous”, caused a variety of obstacles to white tungsten ore dressing. Most white tungsten deposit are associated with calcite, fluorite, barite, such as calcium containing gangue, because of the flotability is close to scheelite so is hard to separate. For many years Petrov method is commonly used for the white tungsten flotation method, namely high temperature flotation process, this process must be heating flotation, high energy consumption, the operation is complicated. Following the development of the technology, finally developed a flotation process at room temperature in the 70s.The most representative of flotation process at room temperature is 731 flotation method at room temperature and method of lime, here’s to emphatically introduce lime method. Scheelite flotation pro...

Development Status of Nano Tungsten Carbide Powder in China

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Nanocrystalline cemented carbide is a tool material developed in recent years. It is based on nano tungsten carbide powder . The cemented carbide with high hardness, high wear resistance and high toughness has been produced under the condition of adding proper binder and grain growth inhibitor, its performance is obviously higher than that of conventional cemented carbide. It has been widely used in hard metal materials, cutting tools, micro drills in the electronics industry, precision molds, medical fields and other fields. In the aspect of ultrafine or nanocrystalline cemented carbide, there are only a few countries in the world such as the United States, Japan, Sweden and so on, which can produce alloy with both high hardness (HRA>90) and high strength (>3 200 MPa). The main difficulties come from ultrafine and nano tungsten carbide powder and other raw materials and cemented carbide production process. From 70 to 80s in China began to study the industri...

Tungsten Oxide Nanoparticle as a Catalyst for Malonic Acid Ester Synthesis via Ozonolysis

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Ozonolysis is of great interest to synthetic organic chemistry because it is one of the most efficient tools for oxidatively cleaving carbon-carbon double bonds. Ozonolysis is generally used to prepare biologically active molecules. Therefore, the reactions between ozone and organic compounds continue to be a subject of significant interest from mechanistic, synthetic, and environmental perspectives. The importance of O 3  reactions with alkenes in the troposphere and solution has led to many experimental and theoretical studies of their kinetics and mechanism. Scientists addresses tungsten oxide nanoparticle syntheses for use as a catalyst in the novel one-step malonic acid ester synthesis. Malonic acid ester is directly synthesized and esterified via the ozonolysis of palm olein (palm oil fraction), which comprises 10% linoleic acid as an unsaturated fatty acid. The main advantages of using tungsten oxide nanoparticles as the catalyst for this esterification are to shor...

Nanocrystalline Tungsten Oxide Thick Film Sensor for the Detection of H2S Gas

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Metal oxide semiconductors (MO S ) have been utilized as gas sensing active materials for half a century. One of the most promising solid-state MO S  chemo sensors is n-type semiconducting tungsten oxide-based  gas  sensor.  They  have  demonstrated  novel sensing  properties  such  as  high  sensitivity,  fast response  time  and  low  operation  temperature.  In particular,  pure  or  doped  tungsten  oxide  is  a  promising material for the detection of various substances, e.g., H 2 ,H 2 S,NOx, NH 3  and ethanol. Scientists have investigated  the sensing characteristics  of   tungsten oxide   nanoparticles  to H 2 S  in  the 7 to 200 ppm range at working temperatures of the range of 100–225 ℃.  Semiconductor  gas  sensors  based  on nanocrystalline  WO 3   powders  we...