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The Crystallization of Ammonium Paratungstate

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Ammonium paratungstate (APT) is an important tungsten intermediate product, mainly with white crystals. It have flakes, needles and strips three kind, used in the manufacture of tungsten trioxide or blue tungsten oxide, TP,  also used for manufacturing ammonium metatungstate and other tungsten compounds. Because the production of tungsten oxide, morphology and particle size of tungsten powder has genetic relationship with APT, so the production process is not only to the tungsten APT purification, but also to control the crystal morphology and particle size of paratungstate tungstate. In the 1950s, in the book "Tungsten and Molybdenum Metallurgy" by A.H rickman, used the reaction 5(NH 4 ) 2 O·12WO 3 ·nH 2 O to describe the APT formula, used the evaporation crystallization process to get n = 5 flaky crystal, and used the acid neutralization process for n = 11 needle crystal. After that in China are all using this view, that of ammonium tungst...

Ten Factors Affecting the Ammonium Paratungstate Crystallization(2)

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Ammonium paratungstate (APT) is an important tungsten intermediate product, not only in the purity and process requirements, as well as crystal grain size and crystal distribution requirements. Seemingly negligible some of the objective factors often play a key role in the final product often For these reasons the difference between the least, lost thousands of miles. 6. The impurities in the solution: As the solution P, As, Mo, Si and other impurities easily adsorbed on the crystal growth of the active point, hinder the crystal growth, but also makes the ammonium paratungstate grain thinning, make the quality of deterioration, and easy to enter the product during the evaporation crystallization process, affecting product quality, and even lead to product failure, so in the crystallization process, should take the control of crystallization rate, improve the concentration of NH 4 Cl in ammonium tungstate solution, stirring and washing agents and other methods, to achieve th...

Ten Factors Affecting the Ammonium Paratungstate Crystallization(1)

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Ammonium paratungstate (APT) is an important tungsten intermediate product, mainly white crystals, there are two kinds of flakes or needle-like, used in the manufacture of tungsten trioxide or blue tungsten oxide tungsten powder. The quality of tungsten products depends largely on the chemical purity of APT, particle size and particle size distribution. APT quality standards from the domestic manufacturers, the process and chemical purity are almost the same, but the production of APT products vary widely, this is because APT is a system engineering, not only the purity and process requirements, as well as crystal grain size and crystal distribution requirements, seemingly insignificant on some of the objective factors often play a key role in the final product is often because of these reasons the difference between the least, lost thousands of miles. There are lots of influence factors of ammonium tungstate, mainly include: the temperature of the solution, the degree...